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海洋有机地球化学实验室II
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课题组负责人及老师介绍:
2 B1 R9 z2 c; _6 \4 [' ] 李先国 教授,博士生导师
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冯丽娟教授,硕士生导师 7 ?0 E6 }" B8 h Y5 Z
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张大海 副教授,硕士生导师 ' B4 w1 F& A6 o1 s) { o
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姚硕 讲师 ( Y* t$ a7 X$ L; }2 ]2 L# W
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课题组研究领域与方向 
! E3 u7 ]1 K' D% i 目前课题组主要开展四个方向的研究,分别是:
9 p1 C% h6 c% {: r+ m& A (一)、陆源有机物及其沉积记录:以木质素、正构烷烃、脂质等为特征生物标志物,研究其在海洋中的沉积记录及其环境地球化学意义。
/ o. K4 v3 ], F1 g e (二)、现代有机污染物及其转化机理:通过实验室模拟实验中降解中间产物或/和代谢产物的分析、稳定同位素分馏效应的测定以及理论计算,与现场测定结果相结合,研究典型有机污染物在环境中的来源、分布及其光降解和生物降解机理,结合定量构效关系研究,评价其生态风险。目前已经开展的污染物研究包括多环芳烃(PAH)、多氯联苯(PCB)、多溴联苯醚(PBDE)、德克隆(DP)、塑化剂(PAES)、烷基酚(NP和OP)、微塑料(MP)等。 4 ?# Y/ s. z7 c+ T2 n
(三):海洋资源化学:通过分析海洋来源物质的成分、结构,确定其可能的生物能量来源,判别其使用价值,尤其是潜在价值。通过各种化学方法或手段转化为可持续资源、能源,如浒苔液化、镁盐晶须、人工海水等。针对当前环境氮、硫污染问题,从源头出发,开展气体、液体的除氮、脱硫工艺研究。
/ x% h4 O+ O' |4 s+ A* w$ w. T3 A& s (四)、微生物化学:通过分析海洋来源微生物群落结构、功能基因、次级代谢产物以及中间产物来探索小分子活性物质的生物合成途径、机理,进一步确定元素迁移路径和能量的转化方式,同时探索发现活性天然产物。通过特殊环境来源微生物的驯化,探索微生物在污染物的去除、降解方面的应用。 ! G' c5 Z) h. N8 Q+ D/ U. c
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课题组重要成果
/ v' a/ Y9 r4 K, m 1)Chanjuan Li, Dahai Zhang, Jialin Peng, Xianguo Li*.The effect of pH, nitrate, iron (III) and bicarbonate on photodegradation of oxytetracycline in aqueous solution. Journal of Photochemistry and Photobiology A: Chemistry, 2018, 356: 239–247. # V! f% u# `7 `. Z
2)Yanxia Lin, Wei Deng*, Shengyong Li, Jiafu Li, Guoguang Wang, Dahai Zhang, Xianguo Li*. Congener profile, distribution, sources and ecological risk of parent and alkyl-PAHs in surface sediments of Southern Yellow Sea, China. Science of the Total Environment, 2017, 580: 1309–1317. & j# ^+ g' W# {/ a' S
3)Guoguang Wang, Jialin Peng, Ting Hao, Yao Liu, Dahai Zhang, Xianguo Li*. Distribution and region-specific sources of Dechlorane Plus in marine sediments from the coastal East China Sea. Science of the Total Environment, 2016, 573: 389–396.
2 w' l( F1 i' {7 { 4)Guoguang Wang, Jialin Peng, Dahai Zhang, Xianguo Li*. Characterizing distributions, composition profiles, sources and potential health risk of polybrominated diphenyl ethers (PBDEs) in the coastal sediments from East China Sea. Environmental Pollution, 2016, 213: 468-481.
& m& G0 ^3 ?4 ~5 m 5)Guoguang Wang, Jialin Peng, Xiang Xu, Dahai Zhang, Xianguo Li*. Polybrominated diphenyl ethers in sediments from the Southern Yellow Sea: Concentration, composition profile, source identification and mass inventory. Chemosphere, 2016, 144: 2097-2105. 5 u' a4 q6 |1 S5 F8 n7 U8 d* ]
6)Jiafu Li, Han Dong, Xiang Xu, Bin Han, Xianguo Li*, Chenjian Zhu, Chen Han, Shaopeng Liu, Dandan Yang, Qian Xu, Dahai Zhang*. Prediction of the bioaccumulation of PAHs in surface sediments of Bohai Sea, China and quantitative assessment of the related toxicity and health risk to humans. Marine Pollution Bulletin, 2016, 104: 92-100.
+ w! u- r5 ^6 J" y% k0 }2 J. J 7)Jialin Peng, Guoguang Wang, Dahai Zhang, Dongmei Zhang, Xianguo Li*. Photodegradation of nonylphenol in aqueous solution by simulated solar UV-irradiation: The comprehensive effect of nitrate, ferric ion and bicarbonate. Journal of Photochemistry and Photobiology A: Chemistry, 2016, 326: 9–15.
2 k" v# U ?2 a3 g 8)Yan Zhang, Ying Liu, Han Dong, Xianguo Li, Dahai Zhang*. The nonylphenol biodegradation study by estuary sediment-derived fungus Penicillium simplicissimum. Environmental Science and Pollution Research, 2016, 23(15): 15122–15132. * f) c o% ~, F& ?+ w' Y; M
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